基本情况

姓名:叶保辉

性别:男

出生年月:1964-11

籍贯:海南文昌

职位:现任无机化学研究所教授,博士生导师

联系方式

电话: +86-020-84112469

传真:暂未填写

邮箱:cesybh@mail.sysu.edu.cn

通讯地址:广东省广州市威尼斯官网化学与化学工程学会

邮编:510275

个人网站:暂未填写

教育经历

1994年毕业于威尼斯官网,获博士学位;
1994年10月至1997年10月在香港科技大学作博士后;
1997年10月到威尼斯官网化学与化学工程学会工作,期间获日本学术振兴会(JSPS)资助,在日本九州大学(Kyushu University)作博士后特别研究员(1999,7-2001,6)

工作经历

暂无资料

讲授课程

曾讲授《无机化学》、《应用无机化学》、《无机化学实验》、《配位化学》等本科生、研究生课程

科研方向

研究方向:功能配合物和超分子化学。 主要研究兴趣:(1) 结构新颖的框架、笼状配合物设计和合成及在催化和分离方面的应用;(2) 钌、稀土配合物在传感器和光学材料方面的应用

科研项目

1. 仿生水解酶的模研究(广东省自然科学基金,编号021423398)
2. 手性配合物的识别及组装(教育部,编号31240415001)
3. 金属卟啉分子筛类杂化材料的合成及性质研究 (广东省自然科学基金资助,编号031581)
4. 新型金属卟啉多孔聚合物的合成及性质研究 (国家自然科学资助,编号20371052)

获奖情况

1. 1996年“混配配合物的生物功能、作用机制及其应用探索”1996年获广东省自然科学一等奖。(第三完成人)
2. 1998年“金属酶体系的结构、机制和模拟研究”获国家教育部科技进步二等奖(基础类)。(第三完成人)
3. 200年“金属酶模型化合物的结构、生物功能、作用机制之间规律性” 获中国高校自然科学二等奖。(第四完成人)

论著一览

1. Template Trapping and Crystal Structure of the Magic Number (H2O)21?Cluster in the Tetrahedral Hole of a Nanoscale Global Ion Packed in a Face-Centered Cubic PatternMan-Li?Cao, Jin-Ji?Wu, Hao-Jun?Mo,?Bao-Hui?Ye*,?J. Am. Chem. Soc.?2009,?131, 3458-3459.?
2. Characterization of a Dinuclear MnV=O Complex and Its Efficient Evolution of O2?in the Presence of Water Y. Shimazaki, T. Nagano, H. Takesue,?Bao-Hui Ye, F. Tani, Y. Naruta,?Angew. Chem. Int. Ed.?2004,43, 98-100.?
3. Metal-organic Molecular Architectures with 2,2’-Bipyridyl-like and Carboxylate LigandsBao-Hui Ye, Ming-Liang Tong, Xiao-Ming Chen*,?Coord. Chem. Rev.?2005,?249, 545-565.?
4. Spontaneous Chiral Resolution of?mer-[CoII(N,N,O-L3)2] Enantiomers Mediated by?p-pInteractionsJin-Ji Wu, Man-Li Cao,?Bao-Hui Ye*,?Chem. Commun., 2010,?46, 3687-3689.?
5.?Interlocking of Molecular Rhombi into a 2D Polyrotaxane Network via p-p Interactions. Crystal Structure of [Cu2(bpa)2(phen)2(H2O)2].2H2O (bpa2- = biphenyl-4,4’-dicarboxylate, phen = 1,10-phenanthroline)Gao-Feng Liu,?Bao-Hui Ye, Y.-H. Liu, Xiao-Ming Chen*,?Chem. Commun.?2002, 1442-1443.?
6. Novel Dimanganese(II) Complexes with (m-H2O)(m-OAc)2?Bridges. Model for Dimanganese Enzymes?Bao-HuiYe, T. Mak, I. D. Williams and Xiao-Yuan Li*,?Chem. Commun.?1997, 1813-1814.?
7. Formation of a Novel Tetranuclear Iron(III) Complex with a m4-PO4?Bridge from 4-Nitrophenyl Phosphate?Bao-Hui Ye, Xiao-Yuan Li*, Feng Xue and T. C. W. Mak,?Chem. Commun.?1997, 2407-2408.?
8. Ruthenium(II) 2,2′-Bibenzimidazole Complex as a Second-SphereReceptor for Anions Interaction and Colorimeter Ying Cui, Yan-Li Niu, Man-Li Cao, Ke Wang, Hao-Jun Mo, Yong-Rui Zhong, and?Bao-Hui Ye*,Inorg. Chem.?2008,?47, 5616-5624?
9. Assembly of a Cubic Nanocage Co8L12?and a Hydrogen-Bonded 3D NbONet Based on the [(HCO3)2]2-?Synthon and Water Man-Li Cao, Hong-Guo Hao, Wei-Xiong Zhang, and?Bao-Hui Ye*,Inorg. Chem,?2008,?47, 8126-8133?
10. A Copper(II) Ion-Selective ON-OFF Type Fluoroionophore Based on Zinc Porphyrin-Dipyridylamino?Yan-Qin Weng, Fan Yue, Yong-Rui Zhong and?Bao-Hui Ye*,?Inorg. Chem.2007,?46,7749-7755.
11. Anion Selective Interaction and Colorimeter by An Optical Metalloreceptor Based on Ruthenium(II) 2,2’-Biimidazole. Hydrogen Bonding and Proton Transfer.Ying Cui, Hao-Jun Mo, Jin-Can Chen, Yan-Li Niu, Yong-Rui Zhong, Kang-Cheng Zheng, and?Bao-Hui Ye*,Inorg. Chem,?2007,46,6427-6436?
12. In Situ Solvothermal Generation of 1,2,4-Triazolates and Related Compounds from Organonitriles and Hydrazine Hydrate: A Mechanism Study Lin?Cheng, Wei-Xiong Zhang,?Bao-Hui Ye*,Jian-Bin Lin,Xiao-Ming Chen*?,?Inorg. Chem.?2007,?46, 1135-1143.?
13. Pillared-layer Microporous Metal-organic Frameworks Constructed by Robust Hydrogen Bonds. Synthesis, Characterization, Magnetic and Adsorption Properties of 2,2’-Biimidazole and Carboxylate Complexes.Bing-Bing Ding, Yan-Qin Weng, Zong-Wan Mao, C.-K. Lam, Xiao-Ming Chen,?Bao-Hui Ye*,Inorg. Chem.?2005,?44, 8836-8845.?
14. Formation of One-dimensional Metal-water Chain Containing Cyclic Water Hexamers,Bao-Hui Ye*, Bing-Bing Ding, Yan-Qin? Weng, Xiao-Ming Chen,?Inorg. Chem.?2004,?43, 6866-6868.?
15. Synthesis and Structural Characterization of Di- and Tetranuclear Zinc Complexes with Phenolate and Carboxylate Bridges. Correlations between?13C NMR Chemical Shifts and Carboxylate Binding Modes?Bao-Hui Ye*, Xiao-Yuan Li, I. D. Williams, Xiao-Ming Chen,Inorg. Chem.?2002,?41, 6426-6431.?
16. The First Two Aqua-bridged Dimagnesium(II) complexes: Structural Models for Active Sites in Dimetallic Hydrolases?Bao-Hui Ye, T. Mak, I. D. Willams and Xiao-Yuan Li*,?J. Chem. Soc. Dalton Trans.?1998, 1935-1936.?
17. Mononuclear Nickel Complexes Assembled into Two-dimensional Networks via Hydrogen Bonds and?p-p?Stacking interactions?Bao-Hui Ye*, Xiao-Ming Chen, Gen-Qiang Xue and Liang-Nian Ji,?J. Chem. Soc. Dalton Trans.1998, 2827-2827.?
18. Mono- and Binuclear Ruthenium(II) Complexes Containing a New Asymmetric Ligand 3-Pyrazyl-as-triazino[5,6-f]1,10-phenanthroline: Synthesis, Characterization and DNA-binding PropertiesXiao-Hua Zou,?Bao-Hui Ye*, Hong Li, Jing-Gang Liu, Ya Xiong and Liang-Nian Ji,?J. Chem. Soc. Dalton Trans.?1999, 1423-1428.?
19. A Novel Method for the Synthesis of Regiospcicically Sulfonated Porphyrin Monomers and Dimmers,?Bao-Hui Ye*, Y. Naruta,?Tetrahedron?2003,?59, 3593-3601.?
20. Syntheses?and Characterization of Aqua-bridged Dimetallic Complexes, M2(m-H2O)(m-OAc)2(Im)4(OAc)2?( M = Mg2+, Mn2+?and Ni2+). Structural Models for the Active Sites of Dimetallic HydrolasesBao-Hui Ye*, I. D. Williams, X.-Y. Li,?J. Inorg.?Biochem.2002,?92, 128-136.

相关成果

1994年“黑曲酶发酵生产葡萄糖酸锌” 获中国专利局发明专利,1996年3月27日公开,公开号:CN119213A。