基本情况

姓名:陈小明

性别:男

籍贯:暂未填写

职位:

教授,博士生导师,现任生物无机与合成化学教育部重点实验室主任,2000年至2004年长江学者特聘教授。2009年当选中国科学会会士

联系方式

电话:+86-020-84113986

传真:暂未填写

邮箱:cxm@mail.sysu.edu.cn

通讯地址:广州市新港西路威尼斯官网化学与化学工程学会

邮编:510275

个人网站:/cxm/

教育经历

1983年获威尼斯官网理学学士学位;
1986年获威尼斯官网理学硕士学位;
1992年获香港中文大学哲学博士学位。

工作经历

主要工作简历:
1986年至1989年在中山医科大会员物化学教研室工作,历任助教、讲师
1992年7月起在威尼斯官网化学与化学工程学会工作
1993年12月晋升副教授,1995年1月晋升教授
2000年至2004年,长江学者特聘教授
2006年至今,生物无机与合成化学教育部重点实验室主任
主要学术兼职:

先后兼任生物无机与合成化学教育部重点实验室主任、中大化学会会长、中国晶体学会副理事长、中国科学会化学部常委及副主任、国家学位委员会化学学科评议组成员、国家基金委化学部专家咨询委员会成员、国际分子筛协会金属有机框架材料(MOF)委员会成员等职务等。

讲授课程

主要讲授《现代无机化学》和《单晶结构分析》等本科生、研究生课程;指导博士后、博士生、硕士生以及国内访问学者的科研工作。

科研方向

功能配位化学与晶体工程研究,特别是配位聚合物、金属有机框架材料等的设计与合成、结构与功能(吸附与分离、催化、光电磁、传感)研究,以及含能分子晶体研究。?

科研项目

暂无资料

获奖情况

2007年国家自然科学奖二等奖(第一完成人):配合物控制合成与晶体工程方法基础研究
2008年汤森路透卓越研究奖?(Thomson?Reuters Research Fronts Award)
2012年发展中国家科学会TWAS化学奖
2012年广东省科学技术奖一等奖(第一完成人): “微孔与磁性配位聚合物研究”
2014年汤森路透高被引用科学家?(Thomson?Reuters Highly Cited Researcher)
2015年汤森路透高被引用科学家?(Thomson?Reuters Highly Cited Researcher)
2016年汤森路透高被引用科学家?(Thomson?Reuters Highly Cited Researcher)
2017年科睿唯安高被引用科学家?(Clarivate?Highly Cited Researcher)
2017年广东省科学技术奖突出贡献奖

论著一览

编写教材:
《单晶结构分析原理与实践》(与蔡继文博士合作),科学出版社,2003年9月第一版,2007年8月第二版。?

陈小明在国际刊物发表的部分论文目录:
Selected Publications of Xiao-Ming Chen:

?1.?Polynuclear CuII12-MIII6?(M = Y, Nd or Gd) complexes encapsulating a ClO4–?anion:?
[Cu12M6(OH)24(pyb)12(H2O)18(ClO4)](ClO4)17·nH2O (pyb = pyridine betaine)
Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N.,?J. Am.?Chem. Soc.?1995,?117, 9600-9601.?PDF

2.?Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties
Tong, M.-L.; Chen, X.-M.; Ye, B.-H.; Ji, L.-N.?Angew. Chem. Int. Ed.?1999,?38, 2237-2240.?PDF

3.?Hydroxylation of?N-heterocycle ligands observed in two unusual mixed-valence CuI-CuII?complexes
Zhang, X.-M.; Tong, M.-L.; Chen, X.-M.,?Angew. Chem. Int. Ed.?2002,?41, 1029-1031.?PDF

4.?A novel, highly electrical conducting, single-component molecular material, [Ag2(ophen)2]?(Hophen = 1H-[1,10]phenanthrolin-2-one)
Zheng, S.-L.;?Zhang, J.-P.; Wong, W.-T.; Chen, X.-M.,?J. Am.?Chem. Soc.?2003,?125, 6882-6883.?PDF

5.?(Review Article)Silver(I)-hexamethylenetetramine?molecular architectures: From self-assembly to designed assembly
Zheng, S.-L.;?Tong, M.-L.; Chen, X.-M.,?Coord. Chem. Rev.?2003,?246, 185-202.?PDF

6.?Two?unprecedented?3-connected three-dimensional networks of copper(I) triazolates:?in-situ?formation of ligands by cycloaddition of nitriles and ammonia
Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.;?Chen, X.-M.,Angew. Chem. Int. Ed.?2004,?43, 206-209.

7.?A new route to supramolecular isomers via molecular templating: nanosized molecular?polygons of?copper(I) 2-methylimidazolates
Huang, X.-C.; Zhang, J.-P.;?Chen, X.-M.,?J. Am.?Chem. Soc.2004,?126, 13218-13219.?PDF

8.?(Review Article)Metal-organic?molecular?architectures with 2,2’-bipyridyl-like and carboxylate ligands
Ye, B.-H.; Tong, M.-L.; Chen, X.-M.,?Coord. Chem. Rev.2005,?249, 545–565.?PDF

9.?Copper(I) 1,2,4-triazolates?and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties
Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.;?Chen, X.-M.,?J.?Am.?Chem. Soc.?2005,?127,?5495-5506.?PDF

10.?Spin-canting and metamagnetism observed in a unique 3D homometallic?molecular?material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets
Zeng, M.-H.; Zhang, W.-X.; Sun,X.-Z.; Chen, X.-M.,?Angew.?Chem. Int. Ed.2005,?44, 3079-3082.?PDF

11.?Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer
Zhang, J.-P.; Lin, Y.-Y.; Zhang,?W.-X.; Chen, X.-M., J.?Am.?Chem. Soc.?2005,?127, 14162-14163.?PDF

12.?Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies
Huang, X.-C.; Lin, Y.-Y.;?Zhang, J.-P.; Chen, X.-M., Angew.?Chem. Int. Ed.?2006,?45, 1557-1559.?PDF

13.?Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior
Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M.,?Angew. Chem. Int. Ed.?2006,?45, 6310-6314.?PDF

14.?(Review Article)Solvothermal?in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry
Chen, X.-M.; Tong, M.-L.,?Acc.?Chem. Res.2007,?40, 162-170.?PDF

15.?A?dynamic?porous?magnet?exhibiting reversible guest-induced magnetic behavior modulation
Cheng, X.-N.; Zhang, W.-X.;Lin, Y.-Y.; Zheng, Y.-Z.;?Chen, X.-M.,?Adv. Mater.?2007,?19, 1494–1498.?PDF

16.?A “star”?antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order
Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.;?Grandjean, F.;?Long, G. J.,?Angew.?Chem. Int. Ed.2007,?46,?6076-6080.?(Highlighted in Nature China)?PDF

17.?Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer
Cheng, X.-N.; Zhang, W.-X.;?Chen, X.-M.,?J. Am.?Chem. Soc.?2007,?129, 15738-15739.?PDF

18.?Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials
Zheng, Y.-Z.; Xue, W.; Zheng, S.-L.; Tong, M.-L.;?Chen, X.-M.,?Adv. Mater.?2008,?20, 1534–1538.?PDF

19.?Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework
Zhang, J.-P.;?Chen, X.-M.,?J. Am.?Chem. Soc.?2008,?130, 6010–6017;?PDF

20.?Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal
Zhang, J.-P.;?Chen, X.-M.,?J. Am.?Chem. Soc.?2009,?131, 5516–5521.?(Highlighted in Nature China)?Link.

21.?(Review Article)Supramolecular isomerism in coordination polymers
Zhang, J.-P.; Huang, X.-C.; Chen, X.-M.,?Chem. Soc.?Rev.2009,?38, 2385–2396.?Link

22.?A highly-connected porous coordination polymer with interesting channel structure and sorption properties
Zhang, Y.-B.; Zhang, W.-X.; Feng, F.-Y.; Zhang, J.-P.;Chen, X.-M.,?Angew.?Chem. Int. Ed.2009,?48,?5287-5290.?Link.

23.?Non-classical active site for enhanced gas sorption in porous coordination polymer
Lin, J.-B.; Zhang, J.-P.;?Chen, X.-M.,?J. Am.?Chem. Soc.?2010,?132, 6654–6656.?Link

24.?Pore surface tailored SOD-type metal-organic zeolites
Zhang, J.-P.; Zhu, A.-X.; Lin, R.-B.; Qi, X.-L.; Chen, X.-M.,?Adv.?Mater.?2011,?22,?1268–1271.?PDF

25.?A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide
Qi, X.-L.; Lin, R.-B.; Chen, Q.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M.,?Chem. Sci.?2011,?2, 2214-2218.?Link.

26.?Geometry analysis and systematic synthesis of isoreticular open frameworks with a unique topology
Zhang, Y.-B.; Zhou, H.-L.; Lin, R.-B.; Zhang, C.; Lin, J.-B.;?Zhang, J.-P.;?Chen, X.-M.,?Nature Commun.?2012,?3, 642.?DOI: 10.1038/ncomms1654.?Link

27.?(Review Article)Metal azolate frameworks: from crystal engineering to functional materials
Zhang, J.-P.; Zhang, Y.-B.; Lin, J.-B.; Chen, X.-M.,?Chem.?Rev.?2012,?112, 1001–1033.?Link

28.?Strong and dynamic CO2?sorption in a flexible porous framework possessing guest chelating claws
Liao, P.-Q.; Zhou, D.-D.; Zhu, A.-X.; Jiang, L.; Lin, R.-B.; Zhang, J.-P.; Chen, X.-M.,?J. Am.?Chem. Soc.?2012,?134,17380-17383.?Link

29.?A porous coordination framework for highly sensitive and selective solid-phase microextraction of non-polar volatile organic?compounds
He, C.-T.; Tian, J.-Y.; Liu, S.-Y.; Ouyang, G.F.; Zhang, J.-P.; Chen, X.-M.,?Chem. Sci.?2013,?4, 351–356.?Link

30.?Turning on the?flexibility?of isoreticular porous coordination frameworks for drastically tunable framework breathing and thermal expansion
Wei, Y.-S.; Chen, K.-J.; Liao, P.-Q.; Zhu, B.-Y.; Lin, R.-B.; Zhou, H.-L.; Wang, B.-Y.; Xue, W.; Zhang, J.-P.; Chen, X.-M.,?Chem. Sci.2013,?4, 1539-1546.?Link

31.?Direct visualization of a guest-triggered crystal deformation based on a flexible ultramicroporous framework
Zhou, H.-L.; Lin, R.-B.; He, C.-T.; Zhang, Y.-B.; Feng, N.-D.; Wang, Q.; Deng, F.; Zhang, J.-P.;Chen, X.-M.,?Nature Commun.?2013,?4, 2534.?DOI: 10.1038 /ncomms3534.?Link

32.?A noble-metal-free porous coordination framework with exceptional sensing efficiency for oxygen
Lin, R.-B.; Li, F.;Liu, S.-Y.; Qi, X.-L.; Zhang, J.-P.; Chen, X.-M.,?Angew.?Chem. Int. Ed.2013,?52, 13429-13433.?Link

33.?(Invited Review)?Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers
Zhang, J.-P.; Liao, P.-Q.; Zhou, H.-L.; Lin, R.-B.; Chen, X.-M.,?Chem. Soc. Rev.?2014,?43, 5789-5814. DOI: 10.1039/C4CS00129J.?Link

34.?Porous Cu(I) triazolate framework and derived hybrid membrane with exceptionally high sensing efficiency for gaseous oxygen
Liu, S.-Y.; Qi, X.-L.; Lin, R.-B.; Cheng, X.-N.; Liao, P.-Q.; Zhang, J.-P.; Chen, X.-M.,?Adv. Funct. Mater.?2014,?24, 5866–5872.?DOI:?10.1002/adfm.201401125.?Link

35.?Visualizing?the?distinctly different crystal-to-crystal structural dynamism and sorption behaviors of interpenetration-direction isomeric coordination networks
He, Chun-Ting; Liao, Pei-Qin; Zhou, Dong-Dong; Wang, Bao-Ying; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming Chen,?Chem. Sci.?2014,?5, 4755.?DOI:10.1039/C4SC01505C.?Link

36.?Switchable guest molecular dynamics in a perovskite-like coordination polymer toward sensitively thermal-responsive dielectric materials
Du, Zi-Yi; Xu, Ting-Ting; Huang, Bo; Su, Yu-Jun; Xue, Wei; He, Chun-Ting;Zhang, Wei-Xiong; Chen, Xiao-Ming;?Angew.?Chem. Int. Ed.2015,?54, 914 –918. DOI: 10.1002/anie.201408491.?Link

37.?Monodentate?hydroxide as a super strong yet reversible active site for CO2?capture from high-humidity flue gas
Liao, Pei-Qin; Zhou, Dong-Dong; Liu, Si-Yang; He, Chun-Ting;Zhang, Wei-Xiong; Jie-Peng Zhang, and Xiao-Ming Chen,Energy Environ. Sci.?2015,?8, 1011-1016. DOI: 10.1039/C4EE02717E.?Link

38.?Self-catalyzed aerobic oxidization of organic linker in porous crystal for on-demand regulation of sorption behaviors
Liao, P.-Q.;?Zhu, A.-X.; Zhang, W.-X.; Zhang, J.-P.; Chen, X.-M.,?Nature Comm.?2015,?6, 6350. doi:10.1038/ncomms7350.?Link

39.?Tuning?fluorocarbon?adsorption on isoreticular metal-organic frameworks for heat transformation applications
Lin, Rui-Biao; Li, Tai-Yang; Zhou, Hao-Long; He, Chun-Ting; Zhang, Jie-Peng; Chen, Xiao-Ming,?Chem. Sci.2015,?6, 2516-2521. DOI: 10.1039/C4SC03985H.?Link

40.?Supramolecular-jack-like guest in ultramicroporous crystal for exceptional thermal expansion behavior
Zhou, Hao-Long; Zhang, Yue-Biao; Zhang, J.-P.; Chen, X.-M.,?Nature Comm.?2015,?6,?6917.?DOI:?doi: 10.1038/ncomms7917.?Link

41.?(Invited Review)?Metal?cluster-based functional porous coordination polymers
Wei-Xiong Zhang, Liao, Pei-Qin; Rui-Biao Lin, Yong-Sheng Wei, Ming-Hua Zeng, Xiao-Ming Chen,?Coord. Chem. Rev.2015,?293–294, 263–278. doi: 10.1016/j.ccr.2014.12.009.?Link?

42.?Exceptional hydrophobicity of a large-pore metal-organic zeolite
Chun-Ting He, Jiang, Lu; Ye, Zi-Ming; Krishna,?Rajamani;?Zhong, Zhen-Song; Liao, Pei-Qin; Xu, Jianqiao; Ouyang, Gangfeng;?Zhang, Jie-Peng; Chen, Xiao-Ming,?J. Am.?Chem. Soc.?2015,?137, 7217–7223.?Link

43.?Coordination templated [2+2+2] cyclotrimerization in porous crystal
Wei,Yong-Sheng; Zhang, Mei; Liao, Pei-Qin; Lin, Rui-Biao; Li, Tai-Yang, Shao, Guang; Zhang, Jie-Peng; Chen, Xiao-Ming,?Nature Commun.?2015,?6,?8348. DOI: 10.1038/ncomms9348.?Link

44.?Efficient purification of ethene by ethane-trapping metal-organic framework?
Liao, Pei-Qin; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming,?Nature Commun.?2015,?6, 8697. doi:10.1038/ncomms9697.?Link

45.?(Hot paper) A metal-organic framework with pore size/shape suitable for strong binding and close packing of methane
Lin, Jiao-Min; He, Chun-Ting; Liu, Yan; Liao, Pei-Qin; Zhou, Dong-Dong; Zhang, Jie-Peng; Chen, Xiao-Ming,?Angew.?Chem. Int. Ed.2016,?55, 4674–4678. DOI: 10.1002/anie.201511006.?Link

46.?An alkaline-stable, metal-hydroxide mimicking metal-organic framework for efficient electrocatalytic oxygen evolution reaction
Lu, Xue-Feng; Liao, Pei-Qin (co-first author); Wang, Jia-Wei;?Wu, Jun-Xi; Chen, Xun-Wei; He, Chun-Ting; Zhang, Jie-Peng; Li, Gao-Ren; Chen, Xiao-Ming,?J. Am.?Chem. Soc.?2016,?138, 8336–8339. DOI: 10.1021/jacs.6b03125.?Link

47.?Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches
Xu, Wei-Jian; He, Chun-Ting; Chen, Shao-Li; Huang, Rui-Kang; Lin, Rui-Biao; Xue, Wei; Luo, Junhua; Zhang, Wei-Xiong; Chen, Xiao-Ming;?Adv. Mater.,?2016,?28, 5886–5890. DOI: 10.1002/adma.201600895.?Link

48.?(Hot paper) Tuning pore size in diamondoid and square lattice networks for size-selective sieving of CO2
Kai-Jie Chen,?David?G. Madden, Tony Pham, Katherine A. Forrest, Amrit Kumar, Qing-Yuan Yang, Wei Xue, Brian Space, John J. Perry IV, Jie-Peng Zhang, Xiao-Ming Chen and Michael J. Zaworotko,?Angew.?Chem. Int. Ed.2016,?55, ?10268–10272. DOI: 10.1002/anie.201603934.?Link

49.?Putting ultrahigh concentration of amine groups into a metal–organic framework for CO2?capture at low pressures
Liao, Pei-Qin;?Chen, Xun-Wei; Liu, Si-Yang; Li, Xu-Yu; Xu, Yan-Tong;Tang, Minni; Rui, Zebao; Ji, Hongbing;?Zhang, Jie-Peng;?Chen, Xiao-Ming;?Chem. Sci.2016,?7, 6528-6533.?DOI:? 10.1039/C6SC00836D.?Link

50.?Flexible, luminescent metal-organic frameworks showing nonlinear/synergistic solid-solution effects on porosity and sensitivity
Liu, Si-Yang; Zhou, Dong-Dong; He, Chun-Ting; Liao, Pei-Qin; Cheng, Xiao-Ning; Xu, Yan-Tong; Ye, Jia-Wen; Zhang, Jie-Peng; Chen, Xiao-Ming,?Angew.?Chem. Int. Ed.2016,?55, 6021–16025. ?DOI:?10.1002/anie.201608439.?Link

51.?Modular and stepwise synthesis of a hybrid metal-organic framework for efficient electrocatalytic oxygen evolution
Shen, Jian-Qiang; Liao, Pei-Qin; Zhou, Dong-Dong; He, Chun-Ting; Wu, Jun-Xi; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming,?J. Am.?Chem. Soc.?2017,?139,?1778–1781. DOI: 10.1021/jacs.6b12353.?Link

52.?A cage-confinement pyrolysis route to ultrasmall tungsten carbide nanoparticles for efficient hydrogen evolution
Xu, Yan-Tong; Xiao, Xiaofen; Ye, Zi-Ming; Zhao, Shenlong; Shen, Rongan;He, Chun-Ting; Zhang, Jie-Peng; Li, Yadong; Chen, Xiao-Ming,?J. Am.?Chem. Soc.?2017,?139,?139,?5285–5288. DOI: 10.1021/jacs.7b00165.?Link

53.?A?molecular?perovskite with switchable coordination bonds for high-temperature multi-axial ferroelectrics
Xu, Wei-Jian; Li, Peng-Fei; Tang, Yuan-Yuan; Zhang, Wei-Xiong; Xiong, Ren-Gen; Chen, Xiao-Ming,J. Am.?Chem. Soc.?2017,?139,?6369–6375. DOI: 10.1021/jacs.7b01334.?Link

54.?Controlling guest conformation for efficient purification of 1,3-butadiene
Liao, Pei-Qin; Huang, Ning-Yu; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming,?Science,?2017,?356, 1193-1196.?DOI: 10.1126/science.aam7232.?Link

55.?A crystalline supramolecular gyroscope with a water molecule as an ultra-small polar rotator modulated by charge-assisted hydrogen bonds
Wang, Li; He, Chun-Ting; Zeng, Ying; Ji, Cheng-Min; Luo, Jun-Hua; Du, Zi-Yi;?Zhang, Wei-Xiong;Chen, Xiao-Ming,?J. Am.?Chem. Soc.?2017,?139,?8086–8089. DOI: 10.1021/jacs.7b02981.?Link

56.?Hyperfine adjustment of flexible pore-surface pockets enables smart recognitions of gas size and quadrupole moment
He, Chun-Ting; Ye, Zi-Ming; Xu, Yan-Tong; Zhou, Dong-Dong; Zhou, Hao-Long; Chen, Da; Zhang, Jie-Peng; Chen, Xiao-Ming,?Chem. Sci.2017,?8,?7560–7565.?DOI: 10.1039/c7sc03067c.?Link

57.?Hydroxide ligands cooperate with catalytic centers in metal-organic frameworks for efficient photocatalytic CO2?reduction
Wang, Yu; Huang, Ning-Yu; Shen, Jian-Qiang; Liao, Pei-Qin; Chen, Xiao-Ming; Zhang, Jie-Peng;?J. Am.?Chem. Soc.?2018,?140,38–41.?Link

58.?Mesoporous metal-organic frameworks with exceptionally high working capacities for adsorption heat transformation
Mo, Zong-Wen; Zhou, Hao-Long;Dong-Dong; Zhou, Rui-Biao Lin, Liao, Pei-Qin; He, Chun-Ting; Zhang, Wei-Xiong;?Chen, Xiao-Ming,Zhang, Jie-Peng;Adv. Mater. ?2018,?30,?1704350.adma.201704350.?Link

59.?Molecular dynamics, phase transition and frequency-tuned dielectric switch of an ionic co-crystal
Liu, Jing-Yan; Zhang, Shi-Yong; Zeng, Ying; Shu,Xia; Du, Zi-Yi;?He, Chun-Ting; Zhang; Wei-Xiong, Chen, Xiao-Ming,?Angew. Chem. Int. Ed.?2018,?10.1002/anie.201802580.?Link